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1: 1,3-diphenyl-2-propenyl acetate With (R)-(S)-Josiphos; bis(dibenzylideneacetone)-palladium(0) in benzene 0.5 h; 2: bis-diphenylphosphine in benzene T=40°C; 48 h; optical yield given as percent eeenantioselective reaction;

1: 1,3-diphenyl-2-propenyl acetate With (R)-(S)-Josiphos; bis(dibenzylideneacetone)-palladium(0) in dichloromethane 0.5 h; 2: bis-diphenylphosphine in dichloromethane T=40°C; optical yield given as percent eeenantioselective reaction;

1: 1,3-diphenyl-2-propenyl acetate With bis(η3-allyl-μ-chloropalladium(II)); (R,R)-DACH phenyl Trost's ligand in tetrahydrofuran 0.5 h; Inert atmosphere; 2: p-toluenesulfinic acid sodium salt in tetrahydrofuran T=20°C; Inert atmosphere; optical yield given as percent eeenantioselective reaction;

bis(η3-allyl-μ-chloropalladium(II)); (2R,5S)-2-(meta-carboran-9-yloxy)-3-phenyl-1,3-diaza-2-phosphabicyclo[3.3.0]octane in tetrahydrofuran T=20°C; 48 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;

triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt; water; diethylamine; palladium diacetate; heptakis(2,6-di-O-methyl)-beta-cyclodextrin T=20°C; Substitution; 20 h;