in acetonitrile-D3 Kinetics; byproducts: C4H8; Complex and allyl bromide was added to an NMR tube which contained CD3CN, after the soln. was degassed, the sealed NMR tube with a reflux condenser was thermostated at 353 K for 100 h;; Detected by NMR-spectroscopy at 298 K; the organic products were analysed by GLC;;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 60, # 2 p. 563 - 570
cislt;Me2Co(bpy)2>&+ in acetonitrile IrradiationESR investigations, further Co-complexes, examination also with allyl bromide; Product distributionMechanism;