反应条件
1: methyl bromide With copper(l) iodide; [(diglyme)NiBr2]; lithium tert-butylate; Pybox in ethylene glycol dimethyl ether; N,N-dimethyl acetamide
Sonogashira Cross-Coupling; 0.0833333 h; Inert atmosphereSchlenk techniqueGlovebox;
2: 4-ethynyl-N,N-dimethylbenzenamine in ethylene glycol dimethyl ether; N,N-dimethyl acetamide
T=20°C; Sonogashira Cross-Coupling; 24 h; Inert atmosphereSchlenk technique;
参考文献
Yi, Jun; Lu, Xi; Sun, Yan-Yan; Xiao, Bin; Liu, Lei
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12409 - 12413
Angew. Chem., 2013 , vol. 125, # 47 p. 12635 - 12639,5
