air in tetrahydrofuran byproducts: butane; N2-atmosphere; treatment of B2H6 with olefin, addn. of MeSH (stirring), injecting small amt. of air (in two steps during 2 h), stirring for 12 h; evapn. of volatiles (reduced pressure), fractional distn. (reduced pressure);
参考文献
Pelter,A. et al.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1976 , p. 2087 - 2090
1: methanethiol With sodium hydride in tetrahydrofuran 0.0333333 h; 2: 1,2-O-isopropylidene-5-O-trifluoromethanesulfanyl-α-D-(-)-xylofuranose in tetrahydrofuran T=20°C;
参考文献
Coll, Mercedes; Pamies, Oscar; Dieguez, Montserrat
Chemical Communications, 2011 , vol. 47, # 32 p. 9215 - 9217
in ethanol; water the thiol was added to soln. of Hg(NO3)2 in EtOH/H2O in a Schlenk tube; soln. was stirred for 12 h in the dark; ppt. was filtered off, washed with cold EtOH and dried in vacuo;
