[Cr(CO)5(THF)] in benzene-d6
byproducts: H2; (N2); react. boron compd. with Cr complex in C6D6 at room temp. for 90 min in the dark; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
[Cp2Ti(η2-Me3SiC2SiMe3)] in toluene
Kinetics; byproducts: hydrogen; soln. of B compd. trasferred to stirred soln. of Zr complex (2 molpercent); reacted at 297 K; monitored by (11)B NMR spectra and volumetric analysis;
in benzene-d6
byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and Cr complex in C6D6 at 8°C in vac. for 1 h or irradn. for 5 min, then standing at room temp. for 1 d in the dark; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
in benzene-d6
byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and W complex in C6D6 at 8°C in vac. for 1 h; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
Ca(N(SiMe3)2)2 in benzene-d6
under N2 or Ar; in NMR tube; C6D6 added to solid mixt. of Me2NHBH3 and Ca compd. (molar ratio 1:1 or 2:1) at ambient temp.; not isolated; monitored by (11)B NMR spectra; (Me2NBH2)3, small amt. of Me2NBH2 (ca. 2percent) and Ca compd. contg. NMe2BH3(1-) obtained;
参考文献
Hill, Michael S.; Hodgson, Marina; Liptrot, David J.; Mahon, Mary F.
Dalton Transactions, 2011 , vol. 40, # 30 p. 7783 - 7790
