1: N-allylbenzamide With ozone in dichloromethane T=-78°C; ozonolysis; 2: 1,1-dibromomethane With diethylamine in dichloromethane T=-78 - 55°C; Ring cleavage; methylenation;
in hexane Kinetics; Irradiation (UV/VIS); irradn. (366 nm) of hexane soln. of Mn2(CO)10, CH2Br2 (0.1 M), and AsPh3 (1.9E-3 to 1.0E-2 M) at 0°C; not isolated; detected by IR;
参考文献
Herrinton, Thomas R.; Brown, Theodore L.
Journal of the American Chemical Society, 1985 , vol. 107, # 20 p. 5700 - 5703
