1: 4-fluoro-1-iodobenzene; silver(I) acetate; palladium dichloride / acetic acid / 44 h / 110 °C 2: sodium tetrahydroborate / methanol / 0.5 h / 0 °C / Inert atmosphere 3: 4-(N,N-dimethlyamino)pyridine; triethylamine / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere 4: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere 5: [2,2']bipyridinyl; lithium aluminium tetrahydride; [Ni0(1,5-cyclooctadiene)2] / tetrahydrofuran / 48 h / 55 °C View Scheme

T=140°C;

1-morpholino-cyclohexene; phosphorus pentachloride in dichloromethane T=0°C; 1 h;

1-phenyl-2,2,2-trifluorodiazoethane; oxygen; thiamine diphosphate in benzene T=20°C; 0.5 h; Irradiationother solvent, reagent; Product distribution;

lithium in ethylene glycol dimethyl ether 6 h; Heating;

T=500°C; P=0.001 - 0.01 Torr; flash vakuum pyrolysis;

3-cyano-N-methylquinolinium perchlorate Photolysis; Quantum yield;

trifluoroacetic anhydride in dichloromethane T=25°C; 10 h;

tris-(dibenzylideneacetone)dipalladium(0); CPME; sodium t-butanolate; Nixantphos T=80°C; 12 h; Inert atmosphere;

1: Br2, Py 2: MCPBA View Scheme