(2,2-二溴乙烯基)苯合成路线 （共 99 条）
反应条件
aluminum oxide; potassium fluoride; copper(l) iodide; triphenylphosphine; nickel
0.05 h; microwave irradiation;
参考文献
Yan, Jincan; Wang, Zhiyuan; Wang, Lei
Journal of Chemical Research, 2004 , # 1 p. 71 - 73
反应条件
1,4-diaza-bicyclo[2.2.2]octane in 1-methyl-pyrrolidin-2-one
T=100°C; 10 h;
参考文献
Tao, Kemei; Zheng, Jianlong; Liu, Zhaogui; Shen, Wang; Zhang, Jiancun
Tetrahedron Letters, 2010 , vol. 51, # 24 p. 3246 - 3249
反应条件
copper(l) iodide; 8-hydroxy-quinoline; potassium carbonate in N,N-dimethyl-formamide
T=110°C; 24 h; Inert atmosphere;
参考文献
Yan, Hong; Lu, Linhua; Sun, Peng; Zhu, Yan; Yang, Hailong; Liu, Defu; Rong, Guangwei; Mao, Jincheng
RSC Advances, 2013 , vol. 3, # 2 p. 377 - 381
反应条件
1: 1,1-dibromostyrene With n-butyllithium in tetrahydrofuran; hexane
T=-78 - 0°C; Corey-Fuchs reaction; Inert atmosphere;
2: With trimethylaluminum in tetrahydrofuran; hexane
T=0°C; Corey-Fuchs reaction; Inert atmosphere;
3: oxirane in tetrahydrofuran; hexane
T=-78 - 20°C; Corey-Fuchs reaction; Inert atmosphere;
参考文献
Smith, Sean M.; Takacs, James M.
Organic Letters, 2010 , vol. 12, # 20 p. 4612 - 4615
反应条件
copper(l) iodide; 8-hydroxy-quinoline; potassium carbonate in N,N-dimethyl-formamide
T=110°C; 24 h; Inert atmosphere;
参考文献
Yan, Hong; Lu, Linhua; Sun, Peng; Zhu, Yan; Yang, Hailong; Liu, Defu; Rong, Guangwei; Mao, Jincheng
RSC Advances, 2013 , vol. 3, # 2 p. 377 - 381
反应条件
in N,N-dimethyl-formamide
T=150°C; 12 h; Inert atmosphere; Overall yield = 72 percent;
参考文献
COUNCIL OF SCIENTIFIC and INDUSTRIAL RESEARCH; AHUJA, Brij, Bhushan; REKULA, Reddy, Santosh; SUDALAI, Arumugam
Patent: WO2013/132520 A1, 2013 ;
Location in patent: Page/Page column 8; 9 ;
反应条件
tris(dibenzylideneacetone)dipalladium (0); tris(4-methoxyphenyl)-phosphine; N-ethyl-N,N-diisopropylamine in N,N-dimethyl-formamide
T=80°C; Stille reaction; 10 h;
参考文献
Shen, Wang; Wang, Le
Journal of Organic Chemistry, 1999 , vol. 64, # 24 p. 8873 - 8879
反应条件
copper(l) iodide; 8-hydroxy-quinoline; potassium carbonate in N,N-dimethyl-formamide
T=110°C; 24 h; Inert atmosphere;
参考文献
Yan, Hong; Lu, Linhua; Sun, Peng; Zhu, Yan; Yang, Hailong; Liu, Defu; Rong, Guangwei; Mao, Jincheng
RSC Advances, 2013 , vol. 3, # 2 p. 377 - 381
反应条件
1: tetrabutyl ammonium fluoride / N,N-dimethyl-formamide / 1 h / 60 °C
2: ruthenium trichloride; oxygen / N,N-dimethyl-formamide / 9 h / 80 °C
View Scheme
参考文献
Fan, Xuesen; He, Yan; Zhang, Xinying; Guo, Shenghai; Wang, Yangyang
Tetrahedron, 2011 , vol. 67, # 34 p. 6369 - 6374
反应条件
sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; tetrakis(triphenylphosphine) palladium(0)
2) THF, RT, 4 h; Yield given. Multistep reaction;
参考文献
Soderquist, John A.; Leon, Gisela; Colberg, Juan C.; Martinez, Isamir
Tetrahedron Letters, 1995 , vol. 36, # 18 p. 3119 - 3122
