(2,2-二溴乙烯基)苯合成路线 （共 99 条）
反应条件
sodium ethanolate; phosphonic acid diethyl ester in ethanol
0.0166667 h; microwave irradiation;
参考文献
Kuang, Chunxiang; Senboku, Hisanori; Tokuda, Masao
Tetrahedron, 2002 , vol. 58, # 8 p. 1491 - 1496
反应条件
lithium tri-n-butylzincate in tetrahydrofuran
T=-85°C; 0.0833333 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Liu, Liu; Wang, Yulei; Zeng, Zhiping; Xu, Pengxiang; Gao, Yuxing; Yin, Yingwu; Zhao, Yufen
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 4 p. 659 - 666
反应条件
tetrakis(triphenylphosphine) palladium(0); tri-n-butyl-tin hydride in dichloromethane
T=25°C; 1 h; Inert atmosphere;
参考文献
Wu, Qiong; Hu, Jian; Ren, Xinfeng; Zhou, Jianrong
Chemistry - A European Journal, 2011 , vol. 17, # 41 p. 11553 - 11558
反应条件
lithium tri-n-butylzincate in tetrahydrofuran
T=-85°C; 0.0833333 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Liu, Liu; Wang, Yulei; Zeng, Zhiping; Xu, Pengxiang; Gao, Yuxing; Yin, Yingwu; Zhao, Yufen
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 4 p. 659 - 666
反应条件
dimethyl benzene-1,4-dicarboxylate; tetra-n-butylammonium tetrafluoroborate in N,N-dimethyl-formamide
effect of proton donors; indirect electrochemical reduction of vinyl halides and related compounds; Product distribution;
参考文献
Gatti, Norberto; Jugelt, Werner; Lund, Henning
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1987 , vol. 41, # 9 p. 646 - 652
反应条件
1: triethylamine; phosphonic acid diethyl ester / 1.5 h / 20 °C
2: copper(l) iodide; palladium diacetate; lithium tert-butylate / 1,4-dioxane / 0.5 h / 120 °C / Microwave irradiation; Inert atmosphere
View Scheme
参考文献
Vabre, Roxane; Chevot, Franciane; Legraverend, Michel; Piguel, Sandrine
Journal of Organic Chemistry, 2011 , vol. 76, # 22 p. 9542 - 9547
反应条件
C17H15ClN7Pd(1+)*F6P(1-); potassium carbonate in water
T=100°C; Suzuki-Miyaura cross-coupling reaction; 12 h;
参考文献
Gu, Shaojin; Xu, Hui; Zhang, Na; Chen, Wanzhi
Chemistry - An Asian Journal, 2010 , vol. 5, # 7 p. 1677 - 1686
反应条件
potassium phosphate; palladium diacetate in polyethylene glycol (PEG-400); water
T=40°C; Suzuki-miyaura coupling; 24 h; Inert atmosphere;
参考文献
Zhu, Yan; Sun, Peng; Yang, Hailong; Lu, Linhua; Yan, Hong; Creus, Marc; Mao, Jincheng
European Journal of Organic Chemistry, 2012 , # 25 p. 4831 - 4837
反应条件
1: tetrabutyl ammonium fluoride / N,N-dimethyl-formamide / 1 h / 60 °C
2: N,N-dimethyl-formamide / 2 h / 60 °C
View Scheme
参考文献
Fan, Xuesen; He, Yan; Zhang, Xinying; Guo, Shenghai; Wang, Yangyang
Tetrahedron, 2011 , vol. 67, # 34 p. 6369 - 6374
反应条件
NiBr2bipy in ethanol
3 h; Heating;
参考文献
Cristau, H. J.; Chabaud, B.; Labaudiniere, R.; Christol, H.
Journal of Organic Chemistry, 1986 , vol. 51, # 6 p. 875 - 878
