2-(1-甲基乙烯)环氧乙烷合成路线 （共 36 条）
反应条件
1: 60 percent / KBr / benzene; aq. HBr / 2 h / 0 °C
2: 81 percent / CHCl3; HCl / 5 h / 0 °C
3: 75 percent / Zn / ethanol / 70 - 80 °C / further dehalogenation agent
View Scheme
参考文献
Kazaryan, P. I.; Avakyan, O. V.; Avakyan, S. V.; Gevorkyan, A. A.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1985 , vol. 21, # 9 p. 988 - 992
Khimiya Geterotsiklicheskikh Soedinenii, 1985 , vol. 21, # 9 p. 1189 - 1193
反应条件
1: 60 percent / KBr / benzene; aq. HBr / 2 h / 0 °C
2: 67 percent / CHCl3; HCl / 5 h / 0 °C
3: 70 percent / Zn / ethanol / 70 - 80 °C / further dehalogenation agent
View Scheme
参考文献
Kazaryan, P. I.; Avakyan, O. V.; Avakyan, S. V.; Gevorkyan, A. A.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1985 , vol. 21, # 9 p. 988 - 992
Khimiya Geterotsiklicheskikh Soedinenii, 1985 , vol. 21, # 9 p. 1189 - 1193
反应条件
1: 60 percent / KBr / benzene; aq. HBr / 2 h / 0 °C
2: 67 percent / CHCl3; HCl / 5 h / 0 °C
3: Zn / ethanol / 70 - 80 °C / further dehalogenation agent
View Scheme
参考文献
Kazaryan, P. I.; Avakyan, O. V.; Avakyan, S. V.; Gevorkyan, A. A.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1985 , vol. 21, # 9 p. 988 - 992
Khimiya Geterotsiklicheskikh Soedinenii, 1985 , vol. 21, # 9 p. 1189 - 1193
反应条件
tin(IV) chloride; triethylamine
1) CH2Cl2, -10 deg C, 1 h, 2) CH2Cl2, 20 deg C, 2 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Kazaryan, P. I.; Avakyan, S. V.; Gevorkyan, A. A.
Journal of Organic Chemistry USSR (English Translation), 1986 , vol. 22, p. 1242 - 1246
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 7 p. 1378 - 1383
反应条件
1: 60 percent / KBr / benzene; aq. HBr / 2 h / 0 °C
2: 80 percent / CHCl3; HCl / 5 h / 0 °C
3: Zn / ethanol / 70 - 80 °C / further dehalogenation agent
View Scheme
参考文献
Kazaryan, P. I.; Avakyan, O. V.; Avakyan, S. V.; Gevorkyan, A. A.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1985 , vol. 21, # 9 p. 988 - 992
Khimiya Geterotsiklicheskikh Soedinenii, 1985 , vol. 21, # 9 p. 1189 - 1193
反应条件
1: 60 percent / KBr / benzene; aq. HBr / 2 h / 0 °C
2: 80 percent / CHCl3; HCl / 5 h / 0 °C
3: 80 percent / Zn / ethanol / 70 - 80 °C / further dehalogenation agent
View Scheme
参考文献
Kazaryan, P. I.; Avakyan, O. V.; Avakyan, S. V.; Gevorkyan, A. A.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1985 , vol. 21, # 9 p. 988 - 992
Khimiya Geterotsiklicheskikh Soedinenii, 1985 , vol. 21, # 9 p. 1189 - 1193
