aluminium trichloride in tetrahydrofuran treatment of phosphole with excess Li in THF (room temp., 2-3 h) followed by AlCl3 (0°C, 30 min), intermediate phospholide anion rected with ClSnMe3 (room temp., 5 min); solidification at -20°C; elem. anal.;
参考文献
Nief, F.; Mathey, F.
Journal of the Chemical Society, Chemical Communications, 1988 , # 12 p. 770 - 771
→
反应条件
in not given Electrochem. Process; during discharge in galvanostatic mode at room temp.; Li as counter electrode, Teklon as separator and 1 M LiPF6 in 1:1 (EC + DMC) as electrolyte; the voltage window: 0.05-1.0 V and 0.05-2.0 V (reversible capacity: ca. 100 mAh/g); detd. by ex situ XRD;
参考文献
Satya Kishore; Varadaraju; Raveau
Journal of Solid State Chemistry, 2004 , vol. 177, # 11 p. 3981 - 3986
in neat (no solvent) Electrochem. Process; galvanostatic tests conducted between 3 and 0 V at const. temp. -15, 25,or 55°C with const. dicharge rates ranging from 1 Li/6 h to 1 Li /75 h; detd. by XRD;
参考文献
Journal of the Electrochemical Society, , vol. 149, # 3 p. A234-A241
→
反应条件
in neat (no solvent)
参考文献
Journal of the Electrochemical Society, , vol. 155, # 3 p. A189-A195
→
反应条件
in neat (no solvent) Electrochem. Process; reaction under galvanostatic conditions in MSb2O6/Li cell at 20 °C; detd. by HRTEM, XRD;
参考文献
Journal of the Electrochemical Society, , vol. 153, # 9 p. A1778-A1787
in tetrahydrofuran; diethyl ether
under N2, Me3SiCH2Cl dissolved in ether, added to stirred suspn. of Li in ether at -50°C, mixt. gradually warmed to -20°C for 1 h, insol. materials filtered at -20°C, soln. cooled to -60°C, BH3 in THF added with stirring; solvent stripped off, distd.;
