in tetrahydrofuran addn. of vinyl bromide and ethylene dibromide to Mg in THF (N2 atmosphere), addn. of further vinyl bromide in THF during 1 h at reflux, decantation, addn. of Sn-compd., refluxing (1 h), cooling room temp.); chromy. (Chromosorb G, 185°C); elem. anal.;
参考文献
Moloney, Mark G.; Pinhey, John T.; Stoermer, Martin J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry, 1990 , p. 2645 - 2656
in neat (no solvent) start of reaction at 550.degree C.; max. formation of Mg2C3 at 680.degree C. and MgC2 at 660.degree C.;;
参考文献
Z. phys. Ch., , vol. 73, p. 528 - 534
→
反应条件
cobalt in neat (no solvent) byproducts: NO; decompn. of Co(CO)3NO and react. of CO with Mg at 900 °C in 3 h; treating with 8 M HCl at 70 °C 1 h, left overnight in the acid atroom temp.; filtering, washing;
参考文献
Journal of Physical Chemistry B, , vol. 105, # 32 p. 7606 - 7611
