in neat (no solvent, gas phase) Electric Arc; Mg vapor reacted with H2S in the presence of a DC electrical discharge (80mA). Cell pressure: 75 mTorr, 10percent H2S in Argon carrier gas. Temperature: 600°C; not isolated, detected by millimeter-wave spectroscopy;
参考文献
Taleb-Bendiab, Amine; Chomiak, Darren
Chemical Physics Letters, 2001 , vol. 334, # 1-3 p. 195 - 199
ethylene dibromide in tetrahydrofuran Mg and (CH2Br)2 in THF were stirred for 15 min under nitrogen, THF soln. of 2-BrC6H4CH2Cl was added during 4 h, mixt. was stirred for 3 h; THF was added, soln. filtered through a coarse glass-filter to remove the residual Mg, filtrate was allowed to settle and decanted leaving magnesacycle as a ppt., soln. was derivatized with Me3SiCl and analyzed by GC-MS;
参考文献
Boer, H. J. R. De; Akkerman, O. S.; Bickelhaupt, F.
Journal of Organometallic Chemistry, 1987 , vol. 321, p. 291 - 306
