in melt Electrolysis; electrolysis of 77.5molpercentKF-7.5molpercentLi2B4O7-15.0percentLi2MoO4 bath, anode: Mo or graphite, cathode: Ni, Cu, Mo, steel or graphite, varying bath temp. and current density; detn. by X-ray;
参考文献
Journal of the Less-Common Metals, , vol. 132, p. 57 - 68
in neat (no solvent) isotermally heated (573-1473 K); I/Mo 0.02-0.4; XRD; elem. anal.; optical anal.;
参考文献
Inorganic Materials (Transl. of Neorg. Mater.), , vol. 19, p. 1376 - 1380
Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy, , vol. 19, p. 1559 - 1563
→
反应条件
in neat (no solvent, solid phase) MoCl5 was ground with NH4Cl, Ca3N2 was added, transfered into stainless steel vessel, heated at ca. 850°C < 1 s; washed with aq. HCl, filtered;
