Sov. J. Coord. Chem. (Engl. Transl.), , vol. 15, p. 67 - 72
Koordinatsionnaya Khimiya, , vol. 15, p. 110 - 115
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反应条件
in not given formation on boiling a soln. of (RuCl(NH3)5)Cl2 with H2SO4 under evolution of H2 and pptn. of a small amount of Ru; discoloration of the soln. to blue; pptn. on cooling;;
参考文献
J. Chem. Soc. (London) A, , p. 1477 - 1482
Intern. Conf. Co-ord. Chem., London 1959, Lectures Abstr., S. 135/136
in not given formation on boiling a soln. of (RuCl(NH3)5)Cl2 with HCl under evolution of H2 and pptn. of a small amount of Ru; discoloration of the soln. to blue; pptn. on cooling;;
参考文献
J. Chem. Soc. (London) A, , p. 1477 - 1482
Intern. Conf. Co-ord. Chem., London 1959, Lectures Abstr., S. 135/136
in tetrahydrofuran under Ar, conventional Schlenk techniques; 10 equiv. of ligand added to soln. of Ru complex in THF; stirred under H2 (1 atm) at room temp. for ca. 3 h; filtered; evapd. to dryness; detd. by (1)H NMR spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 621, # 1-2 p. 246 - 253
in neat (no solvent, solid phase) Ru-complex placed in metal organic chemical vapour deposition reactor, vaporized at 70-75°C under 330 Pa under N2 and H2, deposited on SiO2 on Si substrate heated at 155-175°C for 60-70 min, annealed at450°C for 30 s under H2;
in neat (no solvent, solid phase) Ru-complex placed in metal organic chemical vapour deposition reactor, vaporized at 70-75°C under 330 Pa under N2 and H2, deposited on SiO2 on Si substrate heated at 155-175°C for 60-70 min, annealed at450°C for 30 s under H2;
in neat (no solvent, solid phase) Ru-complex placed in metal organic chemical vapour deposition reactor, vaporized at 70-75°C under 330 Pa under N2 and H2, deposited on SiO2 on Si substrate heated at 155-175°C for 60-70 min, annealed at450°C for 30 s under H2;
in water Application of RuCl3 from aq. soln. to γ-Al2O3, followed by drying in air at 383 K and redn. in a stream of H2 in a flow-through reactor at 723 K for 2 h and then at 773 K for 1 h.;
参考文献
Theoretical and Experimental Chemistry, , vol. 24, p. 68 - 74
Teoreticheskaya i Eksperimental'naya Khimiya, , vol. 24, p. 75 - 81
