in solid
byproducts: CH3(CH2)11SS(CH2)11CH3; (N2); heating silver compd. in a Pyrex tube at 180°C for 2 h, cooling to room temp.; addn. of chloroform/ethanol 1:10 vol., centrifugation for 5 min at 4000 rpm; X-ray diffraction;
silver nitrate in water
Ag and Sb2O3 formed with excess of AgNO3;
参考文献
Reckleben, H.; Guettich, A.
Zeitschrift fuer Analytische Chemie, 1910 , vol. 49, p. 75
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Reckleben, H.
Ber., 1909 , vol. 42, p. 1458 - 1464
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Guettich, A.
Dissert. Leipzig 1909, p. 48-55.
Whitmore, F. C.; Pietrusza, E. W.; Sommer, L. H.
Journal of the American Chemical Society, 1947 , vol. 69, p. 2108 - 2110
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Gmelin Handbook: Si: MVol.C, 34, page 106 - 108
triphenylphosphine in acetonitrile
addn. of AgBF4*0.5C4H8O2 to soln. of complex and PPh3 in dried and distilled solvent, ratio of educts: AgBF4/complex/PPh3=2/1/1, <30s, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
silver nitrate; triphenylphosphine in acetonitrile
addn. of AgNO3 to soln. of complex and PPh3 in dried and distilled solvent, ratio of educts: AgNO3/complex/PPh3=2/1/2, 2h, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
