in toluene
byproducts: H2; under Ar, addn. dry gasous HI to a suspn. of Ag3Nb3(CO)12(dmpe)3, -78°C, slow warming to room temp. (gas evolution at about -40°C); filtered, orange soln. dried in vac., room temp., elem. anal.;
参考文献
Calderazzo, Fausto; Pampaloni, Guido; Englert, Ullrich; Straehle, Joachim
Journal of Organometallic Chemistry, 1990 , vol. 383, p. 45 - 57
in water
reaction at 60.+-.0.1°C, ionic strength 0.5;;
参考文献
Danilczuk, E.
Roczniki Chemii, 1970 , vol. 44, p. 1657 - 1663
→
反应条件
in not given
addition of an excess of Na2SO3 solution;; precipitation within a longer period of time;;
参考文献
Steigmann, A.
Kolloid-Zeitschrift, 1929 , vol. 48, p. 193 - 194
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Gmelin Handbook: Ag: MVol.B3, 11.4.6, page 68 - 68
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Steigmann, A.
Diss. Frankfurt a.M. 1923
in neat (no solvent)
decomposition on heating at high temperatures;;
参考文献
Schulten, A. de
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1887 , vol. 105, p. 811 - 813
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Gmelin Handbook: Ag: MVol.B3, 16.3.6, page 296 - 296
in neat (no solvent, solid phase)
heated to 520 K for 10 min; rinsed in CH3OH; dispersed in toluene; solvent evapd. on Cu grid surface; Ag nanoparticles av. diam..apprx.4 nm; detd. by transmission electron microscopy, temp. dependent diffuse reflectance IR;
参考文献
Lee; Han; Choi; Kim
European Physical Journal D, 2000 , vol. 8, # 3 p. 293 - 296
