in liquid sulphur dioxide no react. of Na with liquid SO2 in a bomb tube from room temp. up to about 70°C;;
参考文献
Gmelin Handbook: S: MVol.B1, 123, page 269 - 271
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Janell, G.
Diss. Greifswald 1939, S. 31
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反应条件
in water byproducts: H2; dissolution of sodium in a concd. aq. soln. of Epsom salt (MgSO4*7H2O) at room temp. under stirring in air; filtration, drying of residue under infra-red lamp, drying of soln. at 100°C;
参考文献
Lakshmanan; Prasad; Ponraju; Krishnan
Journal of Solid State Chemistry, 2004 , vol. 177, # 10 p. 3460 - 3468
alkaline earth chloride in not given byproducts: alkaline earth metal; eqilibrium is investigated;;
参考文献
Welsh; Broderson
Journal of the American Chemical Society, 1915 , vol. 37, p. 828 - 828
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Gmelin Handbook: Na: MVol., 36, page 144 - 145
diethyl malonate in ethanol; toluene Na was dissolved in EtOH at room temp., diethylmalonate was added, toluene was added, soln. phenacyl chloride in toluene was added at room temp.; ppt. was centrifugated and washed with EtOH; powder X-ray diffraction;
diethyl malonate in ethanol; toluene Na was dissolved in EtOH at room temp., diethylmalonate was added, toluene was added, acetyl chloride was added at room temp.; ppt. was centrifugated and washed with EtOH; powder X-ray diffraction;
SeCl4 selenium chloride reacts slowly with Na; upon warming the reaction proceeds vigorously under evolution of heat;;
参考文献
Lenher, V.; Kao, C. H.
Journal of the American Chemical Society, 1926 , vol. 48, p. 1552
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Gmelin Handbook: Na: MVol., 36, page 144 - 145
