in neat (no solvent) heated in Pt crucible up to 1000°C at heating rate of 10°C/min in dry N2 at flow rate of 400 ml/min; monitored by X-ray diffraction;
in [3.3.1]nonane distannane and freshly pptd. Cu heating in nonane in a sealed tube for 40 h at 160°C, liquid fraction decanting off, solid washing with nonane, solvent removing from combined solns.; Me2SnO isolated as Me2SnCl2;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 245 - 252
in neat (no solvent) a mixt. of Sn sulfide and freshly pptd. Cu heating in a sealed tube for6 h at 170°C, liquid product distilling off; purified by distillation in vacuo;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 245 - 252
