in melt placing of mixt. of Al with SnF2 (molar ratio SnF2:Al=1.65) in Fluoroplast-4 ampule, closing by screwed stopper, exposition for 1.00 h at 250°C; various product ratio yields for various conditions; cooling, stirring up in water, collection, drying;
参考文献
Goryacheva; Rakov; Solov'ev
Russian Journal of Inorganic Chemistry, 2001 , vol. 46, # 7 p. 949 - 952
in neat (no solvent) Sn sulfide heating in 1,2-dibromoethane for 30 h at 140°C, solvent removing in vacuo; purified by sublimation in vacuo, identified by elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 245 - 252
in neat (no solvent) byproducts: SnCl4, CO, N2; heated at heating rate of 5 K/min under dry Ar atm. to 600°C; also CH2CO, CH3COCH3, C2H4 as by-products; identified by X-ray diffraction;
参考文献
Russian Journal of Inorganic Chemistry, , vol. 52, # 7 p. 1109 - 1119
Sommer, R.; Schneider, B.; Neumann, W. P.
Liebigs Annalen der Chemie, 1966 , vol. 692, p. 12 - 21
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.2.4.5, page 34 - 36
in neat (no solvent) heating at 1050-1125°C, pressure 200-700 Torr under N2 flow gas; total pressure in inner tube was 200 Torr; heating slowly to 1100.degreeC under redn. atm. with Ar/4percent H2; detd. by SEM, TEM, EDS;
参考文献
Journal of Physical Chemistry B, , vol. 106, # 6 p. 1274 - 1279
