in melt Electrolysis; TiO2 mixed with SiO2 (3:1 molar ratio); ball-milled in anhyd. alcohol (5h); pressed (10 MPa); sintered in air (1150°C, 2 h); used as cat hode in electrolysis of CaCl2 melt (950°C) in Ar at 3.5-4.0 V (1-5 h); XRD; SEM;
in melt Electrochem. Process; electroredn. of TiCl4 soln. in carbamide/acetamide melt (without or with NH4Cl add.) at 100-150°C on steel electrode (current density 1-10 A/dm**2); potentiodynamic monitoring; X-ray diffraction;
参考文献
Soviet Progress in Chemistry (English translation of Ukrainskii Khimicheskii Zhurnal), , vol. 49, # 3 p. 45 - 48
