in gas pulsed-laser ablation of metal atoms into an argon stream containing O2; mechanism discussed (experiments with (18)O2);; condensed at 11 K, not isolated; detn. by IR;
参考文献
Andrews, Lester; Yustein, Jason T.; Thompson, Craig A.; Hunt, Rodney D.
Journal of Physical Chemistry, 1994 , vol. 98, # 26 p. 6514 - 6521
Kinetics; byproducts: oxygen; Ba-atoms and O3-molecules are brought to reaction in crossed molecular beams to form BaO2 and O-atoms at high collision energies. Lower collision energies lead to BaO and O2 as products.; Reaction products are detected by quadrupole mass spectrometry.;
参考文献
Davis, H. Floyd; Suits, Arthur G.; Hou, Hongtao; Lee, Yuan T.
Berichte der Bunsen-Gesellschaft, 1990 , vol. 94, # 11 p. 1193 - 1201
in gas
YAG laser vaporization of Ba (Ba atoms formation) in throat of seeded He supersonic expansion, reaction with seeded gas (benzyl chloride); laser-excited fluorescence monitoring;
参考文献
Cai, Ming Fang; Miller, Terry A.; Bondybey, V. E.
Chemical Physics Letters, 1989 , vol. 158, p. 475 - 479
