copper(l) chloride in neat (no solvent) mixt. of Ge and CuCl was pretreated at 450°C for 1 h under He; mixt. of HCl and allyl chloride was fed at 260°C; not isolated; gas chromd.;
in gas vaporization of Ge (alumina-coated tungsten crucible, 1200-1300°C, 5E-3 Torr), introduction into reaction flask (cooled with liq. N2 during Ge vaporization) together with vapor of org. halide, warming to room temp., standing for 1.5 h; GC-MS, GLC;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 61, p. 1247 - 1250
in neat (no solvent) heating at melting point of AgCl or at 600-700°C;;
参考文献
Brewer, F. M.; Dennis, L. M.
Journal of Physical Chemistry, 1927 , vol. 31, p. 1527 - 1527
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Gmelin Handbook: Ge: MVol., 13, page 40 - 42
