in benzene
byproducts: biphenylbenzene, triphenylphosphine, benzaldehyde; refluxed overnight, inert atm.; evolution of CO2; cooled to room temp., ppt. removed, soln. analysis by GC-MS;
参考文献
Fackler, John P. Jr.; Khan, Md. Nazrul I.; King, Christopher; Staples, Richard J.; Winpenny, Richard E. P.
Organometallics, 1991 , vol. 10, p. 2178 - 2183
in benzene
byproducts: biphenylbenzene, triphenylphosphine, benzaldehyde; refluxed overnight; inert atm.; evolution of CO2; soln. cooled to room temp., filtered from metaqllic gold, filtrate analyzed by GC-MS;
参考文献
Fackler, John P. Jr.; Khan, Md. Nazrul I.; King, Christopher; Staples, Richard J.; Winpenny, Richard E. P.
Organometallics, 1991 , vol. 10, p. 2178 - 2183
in benzene
byproducts: biphenylbenzene, triphenylphosphine, benzaldehyde; refluxed overnight; evolution of CO2; cooled to room temp., filtered, GC-MS;
参考文献
Fackler, John P. Jr.; Khan, Md. Nazrul I.; King, Christopher; Staples, Richard J.; Winpenny, Richard E. P.
Organometallics, 1991 , vol. 10, p. 2178 - 2183
in hydrogen fluoride
HF (liquid); (no H2O); AuF3 and SbF5 placed in reaction tube, HF and AsF3 condensed (-196 °C), warmed to room temp. (AsF5 evoluted, Au ppt. formed), after gas evolution ceased, Xe condensed (-196 °C), tube sealed, cooled to -50 °C;
参考文献
Hwang, In-Chul; Seidel, Stefan; Seppelt, Konrad
Angewandte Chemie - International Edition, 2003 , vol. 42, # 36 p. 4392 - 4395
hydrogen in neat (no solvent)
heating of oven to 300°C; rapid loading with reactor containing (Ir(NH3)5Cl)(AuCl4)Cl in quartz boat; passing of H2 through reactor; exposure for 1 min; removal of reactor from oven; cooling to room temp.; monitoring by XRD;
参考文献
Plyusnin; Baidina; Shubin; Korenev
Russian Journal of Inorganic Chemistry, 2005 , vol. 50, # 12 p. 1834 - 1840
