反应条件
in tetrachloromethane; dichloromethane
to a soln. of the gold complex in CH2Cl2 at -10°C is added a soln. of Br2 in CCl4; the mixt. is stirred for 20 min at the same temp.; the pptd. Au is sepd. off; petroleum ether precipitates a product mixt.; TLC indicates Ph3PO, Ph3PAuBr (content detd. from UV spectrum), and Ph3PAuBr3; pivaloylamide identified from IR spectrum;
参考文献
Perevalova, E. G.; Struchkov, Yu. T.; Kravtsov, D. N.; Kuz'mina, L. G.; Smyslova, E. I.; et al.
Journal of General Chemistry USSR (English Translation), 1988 , vol. 58, p. 54 - 61
Zhurnal Obshchei Khimii, 1988 , vol. 58, p. 62 - 71
