in melt placing of mixt. of V with SnF2 (molar ratio SnF2:V=2.68) in Fluoroplast-4 ampule, closing by screwed stopper, exposition for 1.50 h at 240°C; various product ratio yields for various conditions; cooling, stirring up in water, collection, drying;
参考文献
Goryacheva; Rakov; Solov'ev
Russian Journal of Inorganic Chemistry, 2001 , vol. 46, # 7 p. 949 - 952
Kirshenbaum, A. D; Beardell, A. J.
Thermochimica Acta, 1972 , vol. 4, p. 239 - 248
Full Text View citing articles Show Details
Gmelin Handbook: Mo: SVol.B1, 3.5.5.8, page 118 - 121
in gaseous matrix Irradiation (UV/VIS); metal rod ablation with third harmonic of Nd:YAG laser, ablation plume entraining in supersonic expansion of 5percent NH3/Ar mixt., free-jet expansionskimming to well collimated molecular beam;
参考文献
Ma, Tongmei; Leung; Cheung
Journal of Physical Chemistry A, 2004 , vol. 108, # 25 p. 5333 - 5337
in neat (no solvent, gas phase) generated by the reaction of laser-vaporized vanadium atoms and phenyl hydrazine (0.03percent in He gas); detected by cavity ring-down spectroscopy;
参考文献
Ma, Tongmei; Leung; Cheung
Journal of Physical Chemistry A, 2004 , vol. 108, # 25 p. 5333 - 5337
oxygen in neat (no solvent) react. of V powder with gaseous Cl2 in presence of O2 at ambient temp., faster on heating;; VCl4 contaminated with VOCl3 obtained;;
Cl2 in neat (no solvent) passing Cl2 over vanadium (130°C); elem. anal.;
参考文献
Turevskaya, E. P.; Yanovskii, A. I.; Turova, N. Ya.; Struchkov, Yu. T.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 122 - 130
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 191 - 199
in neat (no solvent) heating under back flow, 800°C;;
参考文献
Gmelin Handbook: V: MVol.B1, 79, page 215 - 217
Full Text Show Details
Anderson, H. H.; Steinbrecher, L.
N.S.A., NYO-8511 (1958) 1/21 1958 , vol. 12, p. 15326
