in neat (no solvent) byproducts: H2; Electrolysis; exclusion of air; addn. of acetylacetone and (n-Bu4N)Br to electrolysisautoclave with V anode, current 100 mV, initial voltage of 8 V, electrolysis for 27 h; concn. (high vac.), recrystn., sublimation;
in neat (no solvent) 24 h in autoclave at 225°C and 10 atm (H2);;
参考文献
Muetterties, E. L.; Castle, J. E.
Journal of Inorganic and Nuclear Chemistry, 1961 , vol. 18, p. 148 - 153
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Gmelin Handbook: V: MVol.B1, 65, page 181 - 184
in melt placing of mixt. of V with SnF2 (molar ratio SnF2:V=2.68) in Fluoroplast-4 ampule, closing by screwed stopper, exposition for 1.50 h at 240°C; various product ratio yields for various conditions; cooling, stirring up in water, collection, drying;
参考文献
Goryacheva; Rakov; Solov'ev
Russian Journal of Inorganic Chemistry, 2001 , vol. 46, # 7 p. 949 - 952
