in solid matrix Irradiation (UV/VIS); heating of water, Ar (excess) and Ca at 465 - 550°C for 1 or 2 hin steel crucible in Ta furnace and cocondensation on mirrored Cu held at 15 K; photolysis of formed matrices with Xe or Hg lamp for 15 min to 2.5 h; reaction mechanisms described; not isolated; detn. by IR; mixture of HCaOH, HCaOCaH and Ca(OH)2 obtained;
参考文献
Kauffman; Hauge; Margrave
High temperature science, 1984 , vol. 18, # 2 p. 97 - 118
in neat (no solvent) atomic calcium was generated by free laser ablation of a rotating Ca sample (1064 nm), 0.7 Torr in scattering cell, 1E-5 Torr in the main chamber; detected by chemiluminescence spectroscopy;
参考文献
Pino; Rinaldi; Ferrero
Chemical Physics Letters, 2001 , vol. 349, # 5-6 p. 463 - 470
in ammonia byproducts: Ag; reduction of AgSCN in liquid NH3 by equimolar amt. of Ca;;
参考文献
Burgess; Holder
Journal of the American Chemical Society, 1937 , vol. 59, p. 460,462
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Gmelin Handbook: Ca: MVol.B3, 142, page 971 - 973
