Ph3PAuOTs; [bis(acetoxy)iodo]benzene; camphor-10-sulfonic acid in methanol; chloroform T=20°C;

sodium hydroxide 6 h; Heating;

1: 3-bromo-4-methoxyacetanilide With boron trifluoride-methanol in methanol T=65°C; Inert atmosphere; 2: With tert.-butylnitrite in methanol T=0°C; 1 h; Inert atmosphere; 3: PhBF3(-)K(+) With palladium diacetate in methanol T=20°C; Suzuki Coupling; 12.25 h; Inert atmosphere;

nickel in tetrahydrofuran T=20°C; Tamao-Kumada-Corriu reaction; 24 h;

1: 79 percent / Br2 / CHCl3 / 16 h / Heating 2: 84 percent / NaOH / 6 h / Heating View Scheme

chloroform; bromine

暂无反应条件数据

ammonia; sodium amide