benzene byproducts: O2; at about 500°C; further byproduct;
参考文献
Levy; Ambrose
Journal of the American Chemical Society, 1959 , vol. 81, p. 249
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Gmelin Handbook: S: SVol.4a/b, 1.1.4.3.2, page 19 - 22
carbon in neat (no solvent) passing SO2 over glowing charcoal at 700 to 850°C (optimum temp.); the react. does not allow an industrial synthesis of CS2;; max. 35percent of S from SO2 obtained as CS2, 56percent as COS and 9percent as S;;
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Berthelot, M.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1883 , vol. 96, p. 298 - 304
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Berthelot
Bulletin de la Societe Chimique de France, 1883 , vol. 40, p. 362 - 367
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Gmelin Handbook: S: MVol.B1, 122, page 267 - 269
anthrazite in neat (no solvent) passing SO2 through a furnace charged with anthrazite; the temp. is 1250°C in the center of the furnace, but only 500 to 700°C at the ends;; turnover into CS2: 85percent;;
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Siller, C. W.
Industrial and Engineering Chemistry, 1948 , vol. 40, p. 1227 - 1233
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Gmelin Handbook: S: MVol.B1, 123, page 269 - 271
formation of varying amt. of H2S by production of S;
参考文献
Galenko, N. P.; Proshkin, A. A.; Chemeris, T. A.; Kovalenko, N. A.; Golubchenko, I. T.
Gazov. Prom., 1960 , vol. 5, # 12 p. 46 - 49
C.A., 1961 , p. 9724
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Gmelin Handbook: S: SVol.4a/b, 1.1.4.3.2, page 19 - 22
in neat (no solvent) byproducts: CO2; equilibrium react. between SO2 and CO (1:2), discussion of 3 equilibria;; no remarkable formation of COS and CS2;;
参考文献
Lepsoe, R.
Industrial and Engineering Chemistry, 1938 , vol. 30, p. 92 - 100