in neat (no solvent) Irradiation (UV/VIS); photochemical decompn. of SO2 in a quartz vessel by light of a quartz-Hg-arc-lamp;;
参考文献
Berthelot, D.; Gaudechon, H.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1910 , vol. 150, p. 1517 - 1521
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Gmelin Handbook: S: MVol.B1, 148, page 323 - 326
in neat (no solvent) decompn. of SO2 by electron impact, complete react. within 40 min (on further react. increasing amounts of O2 obtained), react. rate depending on pressure, independent from temp., mechanism discussed;;
Daubendiek, R. L.; Calvert, J. G.
Environ. Letters, 1975 , vol. 8, p. 103 - 116
C.A., 1975 , vol. 82, p. 174704
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Gmelin Handbook: S: SVol.3, 2.1.8.9.4.5, page 193 - 193
oxygen Kinetics; 20-570°C, partial-pressure of the each components = 100 Torr;
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Tipper, C. F. H.; Williams, R. K.
Transactions of the Faraday Society, 1961 , vol. 57, p. 79 - 86
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Gmelin Handbook: S: SVol.3, 2.1.8.9.4.3, page 190 - 191
Armitage, J. W.; Cullis, C. F.
Combust. Flame, 1971 , vol. 16, p. 125 - 130
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Gmelin Handbook: S: SVol.3, 2.1.8.9.4.4, page 191 - 193
in gaseous matrix byproducts: HO2, O3; addn. of SO2, O2 and Ar to OH-radicals (discharge-flow system), total press. 2-5 Torr, temp. 300 K; not isolated, deposition of products onto a CsI window, identification by IR;
参考文献
Kuo, Yu-Ping; Cheng, Bing-Ming; Lee, Yuan-Pern
Chemical Physics Letters, 1991 , vol. 177, p. 195 - 199
in neat (no solvent) Irradiation (UV/VIS); photochemical decompn. of SO2 in light of a H2-lamp (wave length below 200 nm), about 10°C, 0.5 Torr, mechanism discussed;;
参考文献
Jakowlewa, A.; Kondratjew, W.
Acta Physicochimica URSS, 1940 , vol. 13, p. 241 - 246
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Gmelin Handbook: S: MVol.B1, 76, page 167 - 170
