Smith, B. C.; Smith, G. H.
Journal of the Chemical Society, 1965 , p. 5516 - 5517
Full Text View citing articles Show Details
Gmelin Handbook: S: SVol.3, 2.1.8.9.11, page 206 - 207
in neat (no solvent) byproducts: SO3; prepn. by flow method; Fe2O3 placed to a heated tubular reactor with inert gas passing through it; after achieving a given temp. inert gas flow replaced by flow of Cl2 and SO2 (1:1); linear gas speed was 0.02-0.05 m/s; temp. was 550-750°C; volatiles trapped in cooled traps; monitored by X-ray diffraction and chem. analysis;
参考文献
Derlyukova; Vinokurova
Russian Journal of General Chemistry, 2008 , vol. 78, # 10 p. 1836 - 1842
→
反应条件
in neat (no solvent) Fe2O3 placed into heated tubular reactor through which inert gas passed;after temp. was 300-450°C inert gas was changed to Cl2 + SO2 mix t. (1:1 mol/mol);
参考文献
Derlyukova; Vinokurova; Anufrieva
Russian Journal of Inorganic Chemistry, 2008 , vol. 53, # 9 p. 1371 - 1375
→
反应条件
in neat (no solvent) byproducts: SO3; prepn. by flow method; Bi2O3, Fe2O3 placed to a heated tubular reactor with inert gas passing through it; after achieving a given temp. inert gas flow replaced by flow of Cl2 and SO2 (1:1); linear gas speed was 0.02-0.05 m/s; temp. was 550-750°C; volatiles trapped in cooled traps; monitored by X-ray diffraction and chem. analysis;
参考文献
Derlyukova; Vinokurova; Anufrieva
Russian Journal of Inorganic Chemistry, 2008 , vol. 53, # 9 p. 1371 - 1375
→
反应条件
in neat (no solvent, gas phase) react. in a pulsed ion cyclotron resonance spectrometer at 25°C; not isolated, detected by double resonance expt.;
参考文献
Journal of the American Chemical Society, , vol. 110, # 23 p. 7604 - 7609
