74497-02-2合成路线 （共 11739 条）
反应条件
triethylamine in dichloromethane T=-78 - 20°C; Inert atmosphere;
参考文献
US2011/230495 A1, ;
Page/Page column 17 ;
反应条件
1: hydrochloric acid 2: sulfuric acid monohydrate; fuming nitric acid 3: tin; concentrated hydrochloric acid View Scheme
参考文献
Doebner; v. Miller
Chemische Berichte, 1884 , vol. 17, p. 1703
反应条件
1: F2; TfOH / 20 °C 2: F2; TfOH / 20 °C 3: F2; TfOH / 20 °C View Scheme
参考文献
Alric; Marquet; Billard; Langlois
Journal of Fluorine Chemistry, 2005 , vol. 126, # 4 p. 661 - 667
反应条件
1: aniline With hydrogenchloride; sodium nitrite in water T=0 - 5°C; 0.5 h; 2: acetylacetone With ammonium acetate in ethanol; water T=0 - 5°C; pH=5 - 6;
参考文献
F. HOFFMANN-LA ROCHE AG; ALBERATI, Daniela; GOBBI, Luca; KOERNER, Matthias; KUHN, Bernd; PETERS, Jens-Uwe; RODRIGUEZ SARMIENTO, Rosa Maria; ROGERS-EVANS, Mark; RUDOLPH, Markus
Patent: WO2010/63610 A1, 2010 ;
Location in patent: Page/Page column 48 ;
WO 2010/063610 A1
反应条件
trifluorormethanesulfonic acid; fluorine T=20°C; Title compound not separated from byproducts;
参考文献
Alric; Marquet; Billard; Langlois
Journal of Fluorine Chemistry, 2005 , vol. 126, # 4 p. 661 - 667
反应条件
C36H81Cl3P3Ru T=180°C; Yield given. Yields of byproduct given;
参考文献
Tsuji, Yasushi; Yokoyama, Yasuharu; Huh, Keun-Tae; Watanabe, Yoshihisa
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 9 p. 3456 - 3458
反应条件
ammonium formate; palladium on activated charcoal in methanol; water T=20°C; 0.5 h;
参考文献
Byun, Eunyoung; Hong, Bomi; De Castro, Kathlia A.; Lim, Minkyung; Rhee, Hakjune
Journal of Organic Chemistry, 2007 , vol. 72, # 25 p. 9815 - 9817
反应条件
Cp*Ir(Pro)Cl in toluene T=95°C; 24 h; Inert atmosphereSealed tube;
参考文献
BASF SE; WETZEL, Alexander; Limbach, Michael; Brinks, Marion; Schelwies, Mathias
Patent: US2014/46054 A1, 2014 ;
Location in patent: Paragraph 0143; 0144 ;
反应条件
potassium carbonate in dimethyl sulfoxide T=80°C; 13 h;
参考文献
Srivastava, Sanjay K.; Chauhan, Prem Man Singh; Bhaduri, Amiya P.
Synthetic Communications, 1999 , vol. 29, # 12 p. 2085 - 2091
反应条件
bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; hydrogen; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in methanol; toluene T=125°C; P=30002.4 Torr; 5 h;
参考文献
Ahmed, Moballigh; Seayad, Abdul Majeed; Jackstell, Ralf; Beller, Matthias
Journal of the American Chemical Society, 2003 , vol. 125, # 34 p. 10311 - 10318
