1: SOCl2 View Scheme

暂无反应条件数据

tris-(dibenzylideneacetone)dipalladium(0); di-tert-butyl(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphine in N,N-dimethyl-formamide T=100°C; Inert atmosphere;

1: lithium diisopropyl amide / ethylene glycol dimethyl ether; tetrahydrofuran / 1 h / -35 - 0 °C / |Inert atmosphere 2: potassium carbonate; triphenylphosphine; palladium diacetate / water; ethylene glycol dimethyl ether; tetrahydrofuran / 8 h / 70 °C / |Inert atmosphere 3: lithium diethylamide / ethylene glycol dimethyl ether / 2.42 h / -45 °C / |Inert atmosphere 4: bromine / ethylene glycol dimethyl ether / 4.5 h / 10 - 45 °C / |Inert atmosphere 5: sodium carbonate / water; ethylene glycol dimethyl ether / 6 h / 55 °C / |Inert atmosphere View Scheme

1: lithium diisopropyl amide / ethylene glycol dimethyl ether; tetrahydrofuran / 1 h / -35 - 0 °C / |Inert atmosphere 2: potassium carbonate; triphenylphosphine; palladium diacetate / water; ethylene glycol dimethyl ether; tetrahydrofuran / 8 h / 70 °C / |Inert atmosphere 3: lithium diethylamide / ethylene glycol dimethyl ether / 2.42 h / -45 °C / |Inert atmosphere View Scheme