N,N’-双(2,6-二异丙基苯基)乙烷二亚胺合成路线 （共 7 条）
反应条件
chloro-trimethyl-silane in ethyl acetate T=70°C; 2.75 h; Inert atmosphere;
参考文献
Tang, Pingping; Wang, Weike; Ritter, Tobias
Journal of the American Chemical Society, 2011 , vol. 133, # 30 p. 11482 - 11484
反应条件
in tetrahydrofuran T=20°C; 24 h; Molecular sieveInert atmosphere;
参考文献
Higgins, Eleanor M.; Sherwood, Jennifer A.; Lindsay, Anita G.; Armstrong, James; Massey, Richard S.; Alder, Roger W.; O'Donoghue, Annmarie C.
Chemical Communications, 2011 , vol. 47, # 5 p. 1559 - 1561
反应条件
1.1: chloro-trimethyl-silane / ethyl acetate / 2.75 h / 70 °C / Inert atmosphere 2.1: potassium tert-butylate / tetrahydrofuran / 4 h / 23 °C / Inert atmosphere 2.2: -40 - 23 °C / Inert atmosphere 3.1: cesium fluoride / acetonitrile / 23 - 60 °C / Inert atmosphere View Scheme
参考文献
Tang, Pingping; Wang, Weike; Ritter, Tobias
Journal of the American Chemical Society, 2011 , vol. 133, # 30 p. 11482 - 11484
反应条件
lithium aluminium tetrahydride in tetrahydrofuran T=0 - 20°C;
参考文献
Thomson, Jennifer E.; Campbell, Craig D.; Concellon, Carmen; Duguet, Nicolas; Rix, Kathryn; Slawin, Alexandra M. Z.; Smith, Andrew D.
Journal of Organic Chemistry, 2008 , vol. 73, # 7 p. 2784 - 2791
反应条件
1: 85 percent / sodium borohydride / tetrahydrofuran 2: 59 percent / formic acid / 45 h / Heating 3: 42 percent / KH; dibenzo-18-crown-6 / tetrahydrofuran; various solvent(s) / 5 h / 23 °C View Scheme
参考文献
Arduengo III, Anthony J.; Krafczyk, Roland; Schmutzler, Reinhard; Craig, Hugh A.; Goerlich, Jens R.; Marshall, William J.; Unverzagt, Markus
Tetrahedron, 1999 , vol. 55, # 51 p. 14523 - 14534
反应条件
1.1: toluene / 100 °C 1.2: 47 percent / HCl / toluene; dioxane / 5 h / 70 °C 2.1: 79 percent / KOt-Bu / tetrahydrofuran / 4 h / 20 °C View Scheme
参考文献
Arduengo III, Anthony J.; Krafczyk, Roland; Schmutzler, Reinhard; Craig, Hugh A.; Goerlich, Jens R.; Marshall, William J.; Unverzagt, Markus
Tetrahedron, 1999 , vol. 55, # 51 p. 14523 - 14534
反应条件
1.1: chloro-trimethyl-silane / ethyl acetate / 2.75 h / 70 °C / Inert atmosphere 2.1: potassium tert-butylate / tetrahydrofuran / 4 h / 23 °C / Inert atmosphere 2.2: -40 - 23 °C / Inert atmosphere View Scheme
参考文献
Tang, Pingping; Wang, Weike; Ritter, Tobias
Journal of the American Chemical Society, 2011 , vol. 133, # 30 p. 11482 - 11484
