2-羟基-2-甲基-1-苯基-1-丙酮合成路线 （共 64 条）
反应条件
sodium hypochlorite; potassium bromide; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical in water; toluene T=0 - 5°C; 1.16667 h;
参考文献
CIBA SPECIALTY CHEMICALS HOLDING INC.
Patent: WO2006/5682 A2, 2006 ;
Location in patent: Page 30 ;
反应条件
oxygen; {[Cu(4,4'bipyridine)(BF4)2(H2O)2](4,4'bipyridine)}n/NH2-MNB in ethanol T=20°C; P=760.051 Torr; 72 h;
参考文献
Arai, Takayoshi; Sato, Toru; Kanoh, Hirofumi; Kaneko, Katsumi; Oguma, Koichi; Yanagisawa, Akira
Chemistry - A European Journal, 2008 , vol. 14, # 3 p. 882 - 885
反应条件
oxygen; caesium carbonate; triethyl phosphite in dimethyl sulfoxide T=25°C; P=760.051 Torr; 24 h; Schlenk technique; Reagent/catalystSolvent;
参考文献
Liang, Yu-Feng; Jiao, Ning
Angewandte Chemie - International Edition, 2014 , vol. 53, # 2 p. 548 - 552
Angew. Chem., 2014 , vol. 53, # 2 p. 558 - 562,5
反应条件
trifluoroacetic acid in methanol 2 h;
参考文献
Creary,X.; Geiger,C.C.
Journal of the American Chemical Society, 1982 , vol. 104, p. 4151
反应条件
1: phenyl glyoxylic acid ethyl ester With n-butyllithium; trimethylaluminum; O,N-dimethyl-hydroxylamine hydrochloride in tetrahydrofuran; hexane T=0 - 20°C; 2 h; 2: methylmagnesium bromide in tetrahydrofuran; diethyl ether; hexane T=0 - 20°C; 0.583333 h;
参考文献
Barrios, Francis J.; Springer, Brannon C.; Colby, David A.
Organic Letters, 2013 , vol. 15, # 12 p. 3082 - 3085
反应条件
sodium hydroxide in tetrachloromethane; toluene
反应条件
oxygen; palladium diacetate; 4,7-diphenyl-2,9-dimethyl-1,10-phenanthroline in water T=100°C; 48 h; Product distribution / selectivity;
参考文献
WO2006/5682 A2, ;
Page 30-31 ;
反应条件
potassium tert-butylate in dimethyl sulfoxide IrradiationRT., 4 h, 50 deg C, 19 h;
参考文献
Russell, Glen A.; Ros, Fransisco
Journal of the American Chemical Society, 1985 , vol. 107, # 8 p. 2506 - 2511
反应条件
sodium hydroxide in tetrachloromethane; toluene
反应条件
potassium hydroxide; diethyl ether
参考文献
Journal of the American Chemical Society, , vol. 73, p. 4702,4705
