ammonia

sodium amide Multistep reaction;

Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

1: 33.6 percent / Mn(OAc)3*2H2O; KOAc / 4 h / 115 °C 2: H2, ethylenediamine / tetrahydroborat reduced D-2 nickel (bzw. Ni(OAc)2*4H2O, NaBH4) / methanol; ethanol 3: 70.7 percent / H2 / 5percent Pd/BaSO4 / pyridine; methanol / 20 h / 20 °C 4: LiAlH4 / diethyl ether / 0.5 h / Heating 5: Et3N / diethyl ether / 1 h / 20 °C View Scheme

1: 33.6 percent / Mn(OAc)3*2H2O; KOAc / 4 h / 115 °C 2: H2, ethylenediamine / tetrahydroborat reduced D-2 nickel (bzw. Ni(OAc)2*4H2O, NaBH4) / methanol; ethanol 3: 70.7 percent / H2 / 5percent Pd/BaSO4 / pyridine; methanol / 20 h / 20 °C 4: LiAlH4 / diethyl ether / 0.5 h / Heating View Scheme