2,3,4,6-四邻乙酰基-alpha-d-吡喃葡萄糖三氯乙酰胺合成路线 （共 68 条）
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in dichloromethane 1 h;
参考文献
Ban, Lan; Mrksich, Milan
Angewandte Chemie - International Edition, 2008 , vol. 47, # 18 p. 3396 - 3399
反应条件
1: 1,2,3,4,6-penta-O-acetyl-β-D-glucopyranose With hydrazinium monoacetate in N,N-dimethyl-formamide 2: trichloroacetonitrile With potassium carbonate in N,N-dimethyl-formamide 48 h; Further stages.;
参考文献
Fahmi, Nour Eddine; Dedkova, Larisa; Wang, Bixun; Golovine, Serguei; Hecht, Sidney M.
Journal of the American Chemical Society, 2007 , vol. 129, # 12 p. 3586 - 3597
反应条件
1: 93 percent / hydrazine acetate / dimethylformamide / 0.67 h / 60 °C 2: 76 percent / DBU / CH2Cl2 / 0.5 h / 20 °C View Scheme
参考文献
Carbohydrate Research, , vol. 342, # 15 p. 2309 - 2315
反应条件
1: α-D-glucopyranose pentaacetate With hydrazinium monoacetate in N,N-dimethyl-formamide 2: trichloroacetonitrile With 1,8-diazabicyclo[5.4.0]undec-7-ene in dichloromethane Further stages.;
参考文献
Chang, Cheng-Wei Tom; Hui, Yu; Elchert, Bryan; Wang, Jinhua; Li, Jie; Rai, Ravi
Organic Letters, 2002 , vol. 4, # 26 p. 4603 - 4606
反应条件
1: 99 percent / H2NNH2*AcOH / dimethylformamide / 3 h / 20 °C 2: 85 percent / DBU / CH2Cl2 / 5 h / 20 °C View Scheme
参考文献
Synlett, , # 15 p. 2469 - 2471
反应条件
1: 90 percent / H2O; NIS / H2SO4-silica / CH2Cl2 / 0.5 h / 0 °C 2: 800 mg / DBU / CH2Cl2 / 0.5 h View Scheme
参考文献
Carbohydrate Research, , vol. 341, # 16 p. 2708 - 2713
反应条件
1: 97 percent / Ag2CO3, H2O / acetone / 16 h / Ambient temperature 2: 84 percent / K2CO3 / CH2Cl2 / 64 h / Ambient temperature View Scheme
参考文献
Journal of Medicinal Chemistry, , vol. 41, # 11 p. 1909 - 1926
反应条件
potassium carbonate in dichloromethane 48 h; Ambient temperaturevarious times; Product distribution;
参考文献
Liebigs Annalen der Chemie, , # 7 p. 1343 - 1357
反应条件
1: 15 percent / 5 mol percent HgSO4 / methanol; H2O / 22 h / 20 °C 2: DBU / 7.5 h / 0 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 37, # 3 p. 367 - 370
反应条件
1: pyridine 2: hydrogen bromide; acetic acid 3: Ag2CO3; water / acetone 4: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane View Scheme
参考文献
Organic and Biomolecular Chemistry, , vol. 11, # 15 p. 2421 - 2444
