(+/-)-2,2-二溴-1,1-二联萘合成路线 （共 37 条）
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane T=0°C; 0.166667 h; 2: With methanol in tetrahydrofuran; hexane 0.166667 h;
参考文献
Beilstein Journal of Organic Chemistry, , vol. 5, art. no. A16
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethanol; toluene T=100°C; 24 h; Further byproducts given. Yields of byproduct given;
参考文献
Schilling, Birgit; Kaufmann, Dieter E.
European Journal of Organic Chemistry, 1998 , # 4 p. 701 - 709
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethanol; toluene T=100°C; 24 h;
参考文献
European Journal of Organic Chemistry, , # 4 p. 701 - 709
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethanol; toluene T=100°C; 24 h;
参考文献
European Journal of Organic Chemistry, , # 4 p. 701 - 709
反应条件
1: DBBN With iodine; magnesium in tetrahydrofuran; toluene T=60 - 75°C; 4 h; Inert atmosphere; 2: bis[3,5-bis(trifluoromethyl)phenyl]phosphinyl chloride in tetrahydrofuran; toluene T=60°C; 3 h; 3: With water; ammonium chloride in tetrahydrofuran; toluene T=20°C; 0.166667 h;
参考文献
Chemistry - A European Journal, , vol. 17, # 39 p. 10828 - 10831
反应条件
1: 1.) Mg, 1,2-dibromoethane, I2 / 1.) THF, toluene, from 70 to 80 deg C, 2.) THF, toluene, from 40 to 50 deg C 3: 95 percent / Et3N, trichlorosilane / xylene / 6.5 h / 80 - 130 °C View Scheme
参考文献
Takaya, Hidemasa; Mashima, Kazushi; Koyano, Kinko
Journal of Organic Chemistry, 1986 , vol. 51, # 5 p. 629 - 635
反应条件
1: DBBN With iodine; magnesium in tetrahydrofuran; toluene T=60 - 75°C; 4 h; Inert atmosphere; 2: bis(3,5-dimethylphenyl)bromophosphine in tetrahydrofuran; toluene T=60°C; 3 h;
参考文献
Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan
Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831
反应条件
1: DBBN With iodine; magnesium in tetrahydrofuran; toluene T=60 - 75°C; 4 h; Inert atmosphere; 2: bis(3,5-dimethylphenyl)bromophosphine in tetrahydrofuran; toluene T=60°C; 3 h;
参考文献
Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan
Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831
反应条件
1: DBBN With iodine; magnesium in tetrahydrofuran; toluene T=60 - 75°C; 4 h; Inert atmosphere; 2: bis(3,5-dimethylphenyl)bromophosphine in tetrahydrofuran; toluene T=60°C; 3 h;
参考文献
Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan
Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831
反应条件
copper(l) iodide; sodium azide; N-methyl-2-(methylamino)ethylamine in dimethyl sulfoxide T=100°C; 48 h; Inert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 75, # 14 p. 4887 - 4890
