argentic oxide; nitric acid in 1,4-dioxane 0.0833333 h;

1: 1 M aq. NaOH, silver oxide / 1.) reflux, 0.5 h, 2.) room temperature 2: 31 percent / nitric acid / 2 h / 0 °C 3: 88 percent / H2 / 10percent Pd/C / ethanol / 48 h 4: 1.) conc. HCl, isoamyl nitrite, 2.) propene oxide / 1.) ethanol, 0 deg C, 15 min, 2.) 1,2-dichloroethane, reflux, 10 h 5: aq. 3percent H2SO4 / Heating 6: 80 percent / sodium borohydride / methanol / 2.5 h 7: 15 percent / toluene / 96 h / Heating 8: 71 percent / AgO, aq. 6 N HNO3 / dioxane / 0.08 h View Scheme

1: 31 percent / nitric acid / 2 h / 0 °C 2: 88 percent / H2 / 10percent Pd/C / ethanol / 48 h 3: 1.) conc. HCl, isoamyl nitrite, 2.) propene oxide / 1.) ethanol, 0 deg C, 15 min, 2.) 1,2-dichloroethane, reflux, 10 h 4: aq. 3percent H2SO4 / Heating 5: 80 percent / sodium borohydride / methanol / 2.5 h 6: 15 percent / toluene / 96 h / Heating 7: 71 percent / AgO, aq. 6 N HNO3 / dioxane / 0.08 h View Scheme

1: 88 percent / H2 / 10percent Pd/C / ethanol / 48 h 2: 1.) conc. HCl, isoamyl nitrite, 2.) propene oxide / 1.) ethanol, 0 deg C, 15 min, 2.) 1,2-dichloroethane, reflux, 10 h 3: aq. 3percent H2SO4 / Heating 4: 80 percent / sodium borohydride / methanol / 2.5 h 5: 15 percent / toluene / 96 h / Heating 6: 71 percent / AgO, aq. 6 N HNO3 / dioxane / 0.08 h View Scheme

1: 80 percent / sodium borohydride / methanol / 2.5 h 2: 15 percent / toluene / 96 h / Heating 3: 71 percent / AgO, aq. 6 N HNO3 / dioxane / 0.08 h View Scheme

1: 15 percent / toluene / 96 h / Heating 2: 71 percent / AgO, aq. 6 N HNO3 / dioxane / 0.08 h View Scheme

1: 1.) conc. HCl, isoamyl nitrite, 2.) propene oxide / 1.) ethanol, 0 deg C, 15 min, 2.) 1,2-dichloroethane, reflux, 10 h 2: aq. 3percent H2SO4 / Heating 3: 80 percent / sodium borohydride / methanol / 2.5 h 4: 15 percent / toluene / 96 h / Heating 5: 71 percent / AgO, aq. 6 N HNO3 / dioxane / 0.08 h View Scheme

ammonium cerium(IV) nitrate in acetone; acetonitrile

1: N-bromosuccinimide / peroxyde de benzoyle / CCl4 / Heating 2: d'iodure de sodium / dimethylformamide / 90 °C 3: 41 percent / d'iodure de sodium / dimethylformamide / 24 h / 90 °C 4: 58 percent / nitrate d'ammonium et de cerium / acetonitrile; acetone View Scheme

1: d'iodure de sodium / dimethylformamide / 90 °C 2: 41 percent / d'iodure de sodium / dimethylformamide / 24 h / 90 °C 3: 58 percent / nitrate d'ammonium et de cerium / acetonitrile; acetone View Scheme