in further solvent(s) sputtering react. of Au sheets placed on a stainless steel cathode (dc glow discharge) with CH3CN vapor dild. in Ar; not isolated, detected by microwave spectra;
参考文献
Okabayashi, Toshiaki; Okabayashi, Emi Y.; Koto, Fumi; Ishida, Toshimasa; Tanimoto, Mitsutoshi
Journal of the American Chemical Society, 2009 , vol. 131, # 33 p. 11712 - 11718
in dichloromethane under Ar; CH2Cl2 added to mixt. of Rh complex and Ph3CBF4, added acetonitrile; concd. in vac., pptd. by addn. of Et2O, filtered, washed with Et2O;
参考文献
Journal of the American Chemical Society, , vol. 105, # 25 p. 7288 - 7294
in dichloromethane; acetonitrile byproducts: ferrocene; addn. of ferrocenium tetrafluoroborate (0.20 mmol) to soln. of (Rh2(C2O4)(C8H12)2) (0.20 mmol) in CH2Cl2/CH3CN (1:1);; removal of solvent in vac.; extg. 3 times with ether to remove ferrocene; extg. with CH3CN; concg. ext. and layering with ether; crystn. after 12 h at -20°C; sepn., identification by IR, NMR and elem. anal.;;
