NaY zeolite in neat (no solvent)
carbamide was absorbed on NaY zeolite, 0.5 Torr NO2 was equilibrated for30 min at room temp., heating up to 473 K; monitored and detected by IR in gas and solid phase;
参考文献
Li, Gonghu; Jones, Conrad A.; Grassian, Vicki H.; Larsen, Sarah C.
Journal of Catalysis, 2005 , vol. 234, # 2 p. 401 - 413
Gmelin Handbook: C: MVol.D1, 34.2.2, page 328 - 329
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Normand, C. W. B.; Cumming, A. C.
Journal of the Chemical Society, 1912 , vol. 101, p. 1852 - 1866
Gmelin Handbook: C: MVol.D1, 34.2.2, page 328 - 329
Show Details
Normand, C. W. B.; Cumming, A. C.
Journal of the Chemical Society, 1912 , vol. 101, p. 1852 - 1866
in neat (no solvent)
byproducts: CO2; NaOCN evacuated; HCl gas added at measured pressure; frozen onto NaOCN solid (liq. N2 bath); repeated warming and freezing; deposited on cold substrate (liq. N2 temp.); thin film of HNCO obtained;
参考文献
Lowenthal; Khanna; Moore, Marla H.
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2002 , vol. 58, # 1 p. 73 - 78