1: in toluene T=-60 - 20°C; 5.83333 h; Under nitrogenCooling with acetone-dry ice; 2: With water in tetrahydrofuran; toluene 0.5 h;
参考文献
Arnold, Macklin Brian; Bleisch, Thomas John; Cuff, George William; Ornstein, Paul Leslie; Zimmerman, Dennis Michael
Patent: US2003/225163 A1, 2003 ;
Location in patent: Page 13-14 ;
1: styrene; trimethylaluminum With methylaluminoxane; (-)-(NMI)2ZrCl2 in dichloromethane; water T=23°C; 2: With oxygen in dichloromethane; water T=0 - 23°C; 3: vinyl acetate With Porcine Pancreas Lipase in tetrahydrofuran T=23°C; 7 h; Further stages.;
1: trimethylaluminum; (6R,10R)-6,10,14-trimethyl-pentadec-1-yne With zirconocene dichloride in 1,2-dichloro-ethane 2: 2-chloromethyl-3-methyl-[1,4]-naphthoquinone With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran Further stages.;
