1: trimethylaluminum With 1,4-diaza-bicyclo[2.2.2]octane in toluene T=0°C; 2: α,α,α-trifluoro-m-tolualdehyde With [(R)-1,1'-binaphthyl-2,2'-diyldioxy]{bis[(S)-(1-phenylethyl)]amino}phosphine; bis(acetylacetonate)nickel(II) in tetrahydrofuran T=5°C; 1 h; Title compound not separated from byproducts;
参考文献
Angewandte Chemie - International Edition, , vol. 44, # 15 p. 2232 - 2234
[(R)-1,1'-binaphthyl-2,2'-diyldioxy]{bis[(S)-(1-phenylethyl)]amino}phosphine; bis(acetylacetonate)nickel(II) in tetrahydrofuran; hexane T=-20°C; 6 h; Title compound not separated from byproducts;
参考文献
Biswas, Kallolmay; Prieto, Oscar; Goldsmith, Paul J.; Woodward, Simon
Angewandte Chemie - International Edition, 2005 , vol. 44, # 15 p. 2232 - 2234
in hexane (Ar); std. Schlenk technique; soln. of Me3Al in hexane was slowly added over 5 min to stirred soln. of phenol in hexane; soln. was stirred at 25°C for 1 h; evapd. in vac. overnight;
参考文献
Stapleton, Russell A.; Al-Humydi, Abdulaziz; Chai, Jianfang; Galan, Brandon R.; Collins, Scott
Organometallics, 2006 , vol. 25, # 21 p. 5083 - 5092
