Cp(η5-(1-neomenthyl-4,5,6,7-tetrahydroindenyl))ZrCl2 in dichloromethane
T=22°C; 40 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Parfenova, Lyudmila V.; Berestova, Tatyana V.; Tyumkina, Tatyana V.; Kovyazin, Pavel V.; Khalilov, Leonard M.; Whitby, Richard J.; Dzhemilev, Usein M.
Tetrahedron Asymmetry, 2010 , vol. 21, # 3 p. 299 - 310
bis(η(5)-[1-neomenthylindenyl])zirconium dichloride in dichloromethane
T=22°C; 20 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Parfenova, Lyudmila V.; Berestova, Tatyana V.; Tyumkina, Tatyana V.; Kovyazin, Pavel V.; Khalilov, Leonard M.; Whitby, Richard J.; Dzhemilev, Usein M.
Tetrahedron Asymmetry, 2010 , vol. 21, # 3 p. 299 - 310
ethanol in hexane
dropwise addn. of 70.6 mmol of EtOH in hexane (10 wt.-percent) to distd. AlMe3 (71.5 mmol) in hexane at -75°C with stirring; slow warming to room temp.; performed under Ar;; evapn. under reduced pressure; vac.-distn.; elem. anal.;;
参考文献
Pasynkiewicz, S.; Pikul, S.; Poplawska, J.
Journal of Organometallic Chemistry, 1985 , vol. 293, p. 125 - 130
