in tetrahydrofuran
(N2 or Ar); soln. of Fe complex and alkylhalogenide was refluxed for 3 h; filtered soln. was evapd. to red oil, CHCl3 soln. of the oil was chromd. (Al2O3, CHCl3); identification by IR;
参考文献
Poffenberger, Craig A.; Tennent, Norman H.; Wojcicki, Andrew
Journal of Organometallic Chemistry, 1980 , vol. 191, # 1 p. 107 - 122
1: benzyl chloride With selenium; sodium tetrahydroborate; ethanol; formic acid in N,N-dimethyl-formamide
T=20°C; 4 h;
2: With sodium hydride in N,N-dimethyl-formamide
3: 2-iodo-propane in N,N-dimethyl-formamide
参考文献
Krief, Alain; Trabelsi, Mahmoud; Dumont, Willy; Derock, Michel
Synlett, 2004 , # 10 p. 1751 - 1754
in gaseous matrix
Kinetics; byproducts: (CH3)2CH; supersonic beam of F seeded into He, addn. of alkyl iodide beam (from a gas nozzle, stagnation pressure 45 Torr); react. monitored by MS;
参考文献
Harkin, J. J.; Jarvis, R. D.; Smith, D. J.; Grice, R.
Molecular Physics, 1990 , vol. 71, p. 323 - 344
Bailly
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1919 , vol. 168, p. 561
Bulletin de la Societe Chimique de France, 1919 , vol. <4>25, p. 255
Chem. Zentralbl., 1919 , vol. 90, # III p. 254
