oxygen in water
T=100°C; P=194560 Torr; 20 h; also at different O2 pressures and different reaction times; also in solutions buffered with 0.1 N NaOH; Product distributionKineticsMechanism;
参考文献
Chen, Michael J.; Linehan, John C.; Rathke, Jerome W.
Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3233 - 3236
in neat (no solvent)
byproducts: (NHMe3)Br; absence of air and moisture (vac. line); condensing NMe3 onto mixt. of PF2(NHSiH3) and SiBrH3, warming to room temp., fractional distn., addn. of further NMe3 and SiBrH3 to part involatile at 177 K; fractional distn.;
参考文献
Ebsworth, E. A. V.; Rankin, David W. H.; Wright, John G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1065 - 1069
in neat (no solvent)
byproducts: (NHMe3)Br; absence of air and moisture (vac. line); condensing NMe3 onto mixt. of NH(PF2)2 and SiBrH3, warming to room temp. for 15 s; fractional distn.;
参考文献
Ebsworth, E. A. V.; Rankin, David W. H.; Wright, John G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1065 - 1069
Viville, Pascal; Lazzaroni, Roberto; Pollet, Eric; Alexandre, Michael; Dubois, Philippe
Journal of the American Chemical Society, 2004 , vol. 126, # 29 p. 9007 - 9012
Platoshkin,A.M. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1969 , # 1 p. 98 - 105
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1969 , # 1 p. 112 - 119
