in acetonitrile MeN4Cl adding to the polarographic test soln. prepared from SnCl4*5H2O in acetonitrile containing a ligand in a molar ratio 2:1 and 1 M Pr4NClO4 as a supporting electrolyte under N2; detected polarographically;
Mello, Jesse V.; Finney, Nathaniel S.
Journal of the American Chemical Society, 2005 , vol. 127, # 29 p. 10124 - 10125
→
反应条件
in ethanol; dichloromethane soln. of NMe4Cl in EtOH added to a soln. of (n-Bu4N)2(OsO2(CN)4) in CH2Cl2; pptd. Os complex recrystd. from CH3CN;
参考文献
Preetz, W.; Sartori, C.
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1988 , vol. 43, # 1 p. 94 - 98
→
反应条件
sulfur in acetone Schlenk technique (N2): suspn. of Fe6S6(PEt3)4Cl2, sulfur and (Me4N)Cl in acetone stirred (overnight); ether added to filtrate, -20 ° C (overnight), solid collected, washed (ether), Et3PS (filtrate) detected by 31P NMR;
参考文献
Snyder, Barry S.; Holm, R. H.
Inorganic Chemistry, 1988 , vol. 27, p. 2339 - 2347
in acetonitrile MeN4Cl adding to the polarographic test soln. prepared from SnCl4*5H2O in acetonitrile containing a ligand in a molar ratio 2:1 and 1 M Pr4NClO4 as a supporting electrolyte under N2; detected polarographically;
in acetonitrile MeN4Cl adding to the polarographic test soln. prepared from SnCl4*5H2O in acetonitrile containing a ligand in a molar ratio 2:1 and 1 M Pr4NClO4 as a supporting electrolyte under N2; detected polarographically;
参考文献
Drtil, A.; Meux, Jay; Meux, J. W.; Williams, R. J.; Rogers, J. W.
Polyhedron, 1983 , vol. 2, p. 479 - 484
