in tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (hexane), removal of solvent; elem. anal.;
5,10,15,20-tetrakisphenylporphyrinatoiron(III) chloride in methanol; dichloromethane T=25 - 30°C; Oxygen transfer to (TPP)Fe(III)(Cl) with/without buffer. Chromium complex also investigated, without TBPH and methanol; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 110, # 13 p. 4277 - 4283
(5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato)iron(III)hydrate in water T=30°C; pH between 2 and 13; Rate constantProduct distributionMechanism;
参考文献
Journal of the American Chemical Society, , vol. 111, # 4 p. 1477 - 1483
styrene in tetrachloromethane T=80°C; other solvents; ET, Ea; SN2 and electron transfer mechanisms in the reaction of nucleophiles with peroxides; solvent and substituent effects; reaction in the presence of galvinoxyl scavenger; styrene polymerization; Rate constantThermodynamic dataProduct distribution;
参考文献
Journal of the American Chemical Society, , vol. 105, # 24 p. 7114 - 7122
