lithium aluminium tetrahydride; titanium tetrachloride in tetrahydrofuran T=-5°C; 0.5 h; further reagents: TiCl3-LiAlH4;
参考文献
Garcia, Mariano; Campo, Carmen del; Llama, Emilio F.; Sinisterra, Jose V.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 13 p. 1771 - 1774
lithium aluminium tetrahydride; TiI4 in tetrahydrofuran T=-5°C; 0.5 h; further reagents: TiCl3-LiAlH4, TiCl4-LiAlH4, TiCl3-Mg; various conditions: t (deg C) 66-0; time (min) 60-30;
参考文献
Garcia, Mariano; Campo, Carmen del; Llama, Emilio F.; Sinisterra, Jose V.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 13 p. 1771 - 1774
lithium aluminium tetrahydride; TiI4 in tetrahydrofuran T=-5°C; 0.5 h;
参考文献
Garcia, Mariano; Campo, Carmen del; Llama, Emilio F.; Sinisterra, Jose V.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 13 p. 1771 - 1774
in neat (no solvent) heating of BCl3 and CFCl3 in an evacuated sealed tube at 65°C for 4 h then at 130°C for 33 h; products detected by (11)B- and (19)F-NMR;
in neat (no solvent) heating of BCl3 and CFCl3 in an evacuated sealed tube at 65°C. for 283 h, then 4 h at 130°C; products detected by (11)B- and (19)F-NMR;
in monofluoro-trichloromethane B2Cl4 and 11-fold excess CCl3F were heated in a sealed tube at 65°C for 597 h; products detected by (19)F- and (11)B-NMR;
参考文献
Saulys, D. A; Castillo, J.; Morrison, J. A.
Inorganic Chemistry, 1989 , vol. 28, p. 1619 - 1624
